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A photoactive bimetallic framework for direct aminoformylation of nitroarenes
A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent.
This dataset is associated with the following publication:
Baig, R.B.N., S. Verma, M. Nadagouda , and R. Varma. A photoactive bimetallic framework for direct aminoformylation of nitroarenes. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, UK, 18(4): 1019-1022, (2016).
Complete Metadata
| accessLevel | public |
|---|---|
| bureauCode |
[
"020:00"
]
|
| contactPoint |
{
"fn": "Rajender Varma",
"hasEmail": "mailto:varma.rajender@epa.gov"
}
|
| description | A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent. This dataset is associated with the following publication: Baig, R.B.N., S. Verma, M. Nadagouda , and R. Varma. A photoactive bimetallic framework for direct aminoformylation of nitroarenes. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, UK, 18(4): 1019-1022, (2016). |
| distribution |
[
{
"title": "https://www.rsc.org/suppdata/c5/gc/c5gc02799c/c5gc02799c1.pdf",
"accessURL": "https://www.rsc.org/suppdata/c5/gc/c5gc02799c/c5gc02799c1.pdf"
}
]
|
| identifier | A-37q0-321 |
| keyword |
[
"Aminoformylation",
"Bimetallic framework",
"Earth-abundant materials",
"Nitroarenes",
"Sustainable materials management"
]
|
| license | https://pasteur.epa.gov/license/sciencehub-license.html |
| modified | 2016-02-16 |
| programCode |
[
"020:000"
]
|
| publisher |
{
"name": "U.S. EPA Office of Research and Development (ORD)",
"subOrganizationOf": {
"name": "U.S. Environmental Protection Agency",
"subOrganizationOf": {
"name": "U.S. Government"
}
}
}
|
| references |
[
"https://doi.org/10.1039/c5gc02799c"
]
|
| rights |
null
|
| title | A photoactive bimetallic framework for direct aminoformylation of nitroarenes |