Dataset for Overcoming Analytical Challenges of Other Test Method 50: Analysis of Volatile Fluorinated Compounds in Passivated Canisters from Stationary Source Emissions
This dataset includes spreadsheets containing raw data that were used to create the figures and tables in the publication. Target responses, retention times, and calculations associated with mass spectrometry analyses of Other Test Method 50 canister standards and samples are included. These data were used to construct calibration curves and to calculate percent recoveries and biases of target compounds in the presence of high carbon dioxide (CO2) levels. The dataset also include calculations of average concentrations, standard deviations, relative standard deviations, and percent recoveries for replicate injections to calculate method detection limits (MDLs) and to evaluate percent increases and in sample concentrations by analyzing samples using different thermal desorption method parameters. The data also include an evaluation of method precision, including averages, relative standard deviations, and percent differences between canister samples collected in the absence and presence of high CO2 levels.
This dataset is associated with the following publication:
Wallace, A., S. Jackson, B. Preston, L. Miles, H. Calder, S. Davies, and M. Cumbes. Overcoming analytical challenges of Other Test Method 50: Analysis of volatile fluorinated compounds in passivated canisters from stationary source emissions. JOURNAL OF CHROMATOGRAPHY A. Elsevier Science Ltd, New York, NY, USA, 1759: 1, (2025).
Complete Metadata
| accessLevel | public |
|---|---|
| bureauCode |
[
"020:00"
]
|
| contactPoint |
{
"fn": "Michelle Wallace",
"hasEmail": "mailto:wallace.ariel@epa.gov"
}
|
| description | This dataset includes spreadsheets containing raw data that were used to create the figures and tables in the publication. Target responses, retention times, and calculations associated with mass spectrometry analyses of Other Test Method 50 canister standards and samples are included. These data were used to construct calibration curves and to calculate percent recoveries and biases of target compounds in the presence of high carbon dioxide (CO2) levels. The dataset also include calculations of average concentrations, standard deviations, relative standard deviations, and percent recoveries for replicate injections to calculate method detection limits (MDLs) and to evaluate percent increases and in sample concentrations by analyzing samples using different thermal desorption method parameters. The data also include an evaluation of method precision, including averages, relative standard deviations, and percent differences between canister samples collected in the absence and presence of high CO2 levels. This dataset is associated with the following publication: Wallace, A., S. Jackson, B. Preston, L. Miles, H. Calder, S. Davies, and M. Cumbes. Overcoming analytical challenges of Other Test Method 50: Analysis of volatile fluorinated compounds in passivated canisters from stationary source emissions. JOURNAL OF CHROMATOGRAPHY A. Elsevier Science Ltd, New York, NY, USA, 1759: 1, (2025). |
| distribution |
[
{
"title": "Figure 3_20250725.xlsx",
"mediaType": "application/vnd.openxmlformats-officedocument.spreadsheetml.sheet",
"downloadURL": "https://pasteur.epa.gov/uploads/10.23719/1531889/Figure%203_20250725.xlsx"
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{
"title": "Figure 4_20250725.xlsx",
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"title": "Figure 5_20250728.xlsx",
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}
]
|
| identifier | https://doi.org/10.23719/1531889 |
| keyword |
[
"Other Test Method 50",
"canister sampling",
"gas chromatography-mass spectrometry (GC-MS)",
"per and polyfluoroalkyl substances (PFAS)",
"source air emissions",
"volatile fluorinated compounds"
]
|
| license | https://pasteur.epa.gov/license/sciencehub-license.html |
| modified | 2025-07-31 |
| programCode |
[
"020:000"
]
|
| publisher |
{
"name": "U.S. EPA Office of Research and Development (ORD)",
"subOrganizationOf": {
"name": "U.S. Environmental Protection Agency",
"subOrganizationOf": {
"name": "U.S. Government"
}
}
}
|
| references |
[
"https://doi.org/10.1016/j.chroma.2025.466226"
]
|
| rights |
null
|
| title | Dataset for Overcoming Analytical Challenges of Other Test Method 50: Analysis of Volatile Fluorinated Compounds in Passivated Canisters from Stationary Source Emissions |
