Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US
Nitrapyrin is a nitrification inhibitor that is co-applied with N-fertilizer in agroecosystems. Over the course of one year (March 2016 to June 2017), 192 water samples from seven streams across Iowa and Illinois were analyzed for nitrapyrin, its degradate 6-chloropicolinic acid (6-CPA), and three widely used herbicides acetochlor, atrazine, and metolachlor. Additional environmental samples were collected and analyzed in spring 2017: 63 water samples from eight subsurface drains, and 33 soil samples from a field in Iowa that received direct application of nitrapyrin (only for nitrapyrin and herbicides). Nitrapyrin was detected in all seven streams (56% detection) with concentrations ranging from 4 to 1,200 ng/L; 6-CPA was detected in six of the seven streams (13% detection) with concentrations ranging from 2 to 13 ng/L. Nitrapyrin was detected in only two of the eight subsurface drains and in 10% of drain samples (10% detection), and with concentrations ranginged from 3 to 12 ng/L; 6-CPA was detected in six of the eight subsurface drains and in (33% of drain samples withdetection), and concentrations ranginged from 2 to 6 ng/L. Nitrapyrin was detected in 67% of the soil samples collected, and concentrations ranged from 0.9 to 42 ng/g. Generally, all three herbicides were detected more frequently and at higher concentrations than nitrapyrin in the streams, subsurface drains, and soils. There are 3 csv datasets related to this data release. Please find in each of the child items the data and metadata.
Complete Metadata
| accessLevel | public |
|---|---|
| bureauCode |
[
"010:12"
]
|
| contactPoint |
{
"fn": "Michelle L. Hladik",
"@type": "vcard:Contact",
"hasEmail": "mailto:mhladik@usgs.gov"
}
|
| description | Nitrapyrin is a nitrification inhibitor that is co-applied with N-fertilizer in agroecosystems. Over the course of one year (March 2016 to June 2017), 192 water samples from seven streams across Iowa and Illinois were analyzed for nitrapyrin, its degradate 6-chloropicolinic acid (6-CPA), and three widely used herbicides acetochlor, atrazine, and metolachlor. Additional environmental samples were collected and analyzed in spring 2017: 63 water samples from eight subsurface drains, and 33 soil samples from a field in Iowa that received direct application of nitrapyrin (only for nitrapyrin and herbicides). Nitrapyrin was detected in all seven streams (56% detection) with concentrations ranging from 4 to 1,200 ng/L; 6-CPA was detected in six of the seven streams (13% detection) with concentrations ranging from 2 to 13 ng/L. Nitrapyrin was detected in only two of the eight subsurface drains and in 10% of drain samples (10% detection), and with concentrations ranginged from 3 to 12 ng/L; 6-CPA was detected in six of the eight subsurface drains and in (33% of drain samples withdetection), and concentrations ranginged from 2 to 6 ng/L. Nitrapyrin was detected in 67% of the soil samples collected, and concentrations ranged from 0.9 to 42 ng/g. Generally, all three herbicides were detected more frequently and at higher concentrations than nitrapyrin in the streams, subsurface drains, and soils. There are 3 csv datasets related to this data release. Please find in each of the child items the data and metadata. |
| distribution |
[
{
"@type": "dcat:Distribution",
"title": "Digital Data",
"format": "XML",
"accessURL": "https://doi.org/10.5066/P91OESMG",
"mediaType": "application/http",
"description": "Landing page for access to the data"
},
{
"@type": "dcat:Distribution",
"title": "Original Metadata",
"format": "XML",
"mediaType": "text/xml",
"description": "The metadata original format",
"downloadURL": "https://data.usgs.gov/datacatalog/metadata/USGS.5afca5e3e4b0da30c1bc2177.xml"
}
]
|
| identifier | http://datainventory.doi.gov/id/dataset/USGS_5afca5e3e4b0da30c1bc2177 |
| keyword |
[
"Corn Belt region",
"Fall",
"Illinois",
"Iowa",
"Spring",
"Summer",
"USGS:5afca5e3e4b0da30c1bc2177",
"United States",
"Winter",
"agricultural soils",
"agriculture",
"contaminant transport",
"ecotoxicity",
"herbicide",
"nitrapyrin",
"stormwater",
"stream discharge",
"tile drainage",
"water quality",
"year"
]
|
| modified | 2022-03-31T00:00:00Z |
| publisher |
{
"name": "U.S. Geological Survey",
"@type": "org:Organization"
}
|
| spatial | -96.817016601261, 36.518114360445, -87.236938476645, 43.508403682242 |
| theme |
[
"Geospatial"
]
|
| title | Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US |
