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                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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            <gco:CharacterString>RB2205, PNE</gco:CharacterString>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Cruise ID</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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          </gmd:thesaurusName>
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            <gco:CharacterString>33RO20221101</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>EXPOCODE</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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        <gmd:MD_Keywords>
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          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Ocean Acidification Search Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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          </gmd:thesaurusName>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>SOOP Cruises</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Reference Section ID</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Research Cruises</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Research Projects</gco:CharacterString>
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              <gmd:date gco:nilReason="inapplicable" />
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      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/a65cfcfa-1028-4cc8-a4d5-9e78f487a612" xlink:actuate="onRequest">EARTH SCIENCE &gt; ATMOSPHERE &gt; ATMOSPHERIC CHEMISTRY &gt; CARBON AND HYDROCARBON COMPOUNDS &gt; ATMOSPHERIC CARBON DIOXIDE &gt; PARTIAL PRESSURE OF CARBON DIOXIDE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/08fd82a1-4370-46a2-82ea-94c0f91498a7" xlink:actuate="onRequest">EARTH SCIENCE &gt; ATMOSPHERE &gt; ATMOSPHERIC PRESSURE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/1d8525f0-0cfc-4d59-8677-da5c8038deb7" xlink:actuate="onRequest">EARTH SCIENCE &gt; CLIMATE INDICATORS &gt; ATMOSPHERIC/OCEAN INDICATORS &gt; SURFACE SALINITY</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/26afa886-4866-4536-be3a-6f9db9aacd97" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; CARBON DIOXIDE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/46206e8c-8def-406f-9e62-da4e74633a58" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; WATER TEMPERATURE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7e95b5fc-1d58-431a-af36-948b29fa870d" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; SALINITY/DENSITY &gt; SALINITY</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
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              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
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                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
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                            <gco:CharacterString>MD</gco:CharacterString>
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                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
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                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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            <gco:CharacterString>Surface underway</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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            <gco:CharacterString>PRES_ATM@SSP_hPa</gco:CharacterString>
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            <gco:CharacterString>SAL_permil</gco:CharacterString>
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            <gco:CharacterString>SST_C</gco:CharacterString>
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          <gmd:keyword>
            <gco:CharacterString>fCO2_SW@SST</gco:CharacterString>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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        </gmd:MD_Keywords>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/0bf12743-3ab8-4be7-9b48-b565723ed0ad" xlink:actuate="onRequest">BAROMETERS &gt; BAROMETERS</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7aecabfb-0047-484f-8396-efc0da16bc20" xlink:actuate="onRequest">CO2 ANALYZERS &gt; CO2 ANALYZERS</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/d8efbcb9-9ab3-4016-b7ff-6426cd0bf545" xlink:actuate="onRequest">EQUILIBRATORS</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/ed79ec7b-a2df-4948-9877-b75e1fcb8782" xlink:actuate="onRequest">SALINOMETERS</gmx:Anchor>
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          <gmd:keyword>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
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              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
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                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
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                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="platform">platform</gmd:MD_KeywordTypeCode>
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                <gco:CharacterString>Global Change Master Directory (GCMD) Platform Keywords</gco:CharacterString>
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                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/download/276415</gmd:URL>
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                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
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                    <gco:CharacterString>FTP</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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                <gco:CharacterString>NCEI Accession 0276415 v1.1 was published.</gco:CharacterString>
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                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0276415/1.1</gmd:URL>
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                                    <gco:CharacterString>NCEI Accession 0276415 v1.1</gco:CharacterString>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: fCO2_SW@SST;
Unit: uatm;
Observation type: Surface underway;
Measured or calculated: Measured;
Sampling instrument: Seawater pump;
Location of seawater intake: Bow;
Analyzing instrument: Infrared Analyzer: LI-COR model 6262;
Detailed sampling and analyzing information: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., &amp; Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005;
Equilibrator type: Spray head above dynamic pool, with thermal jacket;
Equilibrator volume: 0.95 L (0.4 L water, 0.55 L headspace);
Is the equilibrator vented or not: Vented;
Water flow rate: 1.5 - 2.0 L/min;
Gas flow rate: 70 - 150 ml/min;
How was temperature inside the equilibrator measured: Hart Scientific model 1523 digital thermometer;
How was pressure inside the equilibrator measured: External Setra 270 connected to the exit of the analyzer;
Drying method for gas: Gas stream passes through a thermoelectric condenser (~5 C) and then through a Perma Pure (Nafion) dryer before reaching the analyzer (90% dry).;
SEA CO2 gas detector manufacturer: Licor, Inc;
SEA CO2 gas detector model: Licor 6262;
SEA CO2 gas detector resolution: Accuracy: ± 2 μatm in fCO2_SW;
SEA CO2 gas detector uncertainty: Precision: ± 0.01 μatm in fCO2_SW;
Standardization technique: The system runs a full cycle in approximately 7 hours. The cycle starts with 4 standard gases, then measures three rounds of 6 atmopherice samples followed by 50 surface water samples. Each new gas is flushed through the Licor Analyzer for 2 minutes prior to a stop-flow measurement.;
Standardization frequency: Every 7 hours;
Standard gas manufacturer: Standard gases are supplied by NOAA Earth System Research Laboratory, Global Monitoring Division, in Boulder, CO, and are directly traceable to the WMO scale.;
Standard gas concentration: The analyzer is calibrated every 3.5 hours using field standards that were calibrated with primary standards that are directly traceable to the WMO X2007 scale. Ultra-High Purity air (0.0 ppm CO2) and the high standard are used to zero and span the LI-COR analyzer. Std 1: CB09731, 232.26 ppm, owned by ESRL, used every ~5.0 hours. Std 2: JB03268, 384.30 ppm, owned by AOML, used every ~5.0 hours. Std 3: CC720367, 430.75 ppm, owned by ESRL, used every ~5.0 hours. Std 4: CB11243, 591.87 ppm, owned by ESRL, used every ~5.0 hours. Std 5: LL100000, 0.00 ppm, owned by AOML, used every ~20.0 hours.;
Standard gas uncertainty: 0.01 ppm;
Water vapor correction method: Details of the data reduction are described in Pierrot, et.al. (2009).;
Temperature correction method: Details of the data reduction are described in Pierrot, et.al. (2009).;
At what temperature was pCO2 reported: In situ sea surface temperature;
Uncertainty: 0.01C;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value;
Method reference: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., &amp; Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005;
Researcher name: Denis Pierrot;
Researcher institution: NOAA/AOML</gco:CharacterString>
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
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                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST_C;
Unit: degrees celcius;
Observation type: Surface Underway;
Sampling instrument: Seabird;
Analyzing instrument: SBE-45, Seabird, Inc.;
Detailed sampling and analyzing information: Ship's TSG in hydro lab near the CO2 system;;
Uncertainty: Accuracy: ± 0.002 (°C), Precision: 0.0002 (°C); Manufacturer's Resolution is taken as Precision; Maintained by ship.;
Researcher name: Denis Pierrot;
Researcher institution: NOAA/AOML</gco:CharacterString>
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea Surface Salinity;
Abbreviation: SAL_permil;
Observation type: Surface Underway;
Sampling instrument: Seabird;
Analyzing instrument: SBE 45, Seabird, Inc.;
Uncertainty: Accuracy: ± 0.005; Precision: 0.0002;
Researcher name: Denis Pierrot;
Researcher institution: NOAA/AOML</gco:CharacterString>
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          <gmd:processStep>
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              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Atmospheric Pressure;
Abbreviation: PRES_ATM@SSP_hPa;
Unit: hPa;
Sampling instrument: Vaisala, PTB330;
Detailed sampling and analyzing information: Location: On bulkhead exterior on the port side of the radio room aft of the bridge at ~14 m above the sea surface;
Uncertainty: Accuracy: +/- 0.2 hPa; Precision: 0.08 hPa;
Researcher name: Denis Pierrot;
Researcher institution: NOAA/AOML</gco:CharacterString>
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        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
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      <gmd:contact>
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            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
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    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
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          <gmi:identifier>
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              <gmd:code>
                <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
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          <gmi:type>
            <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>instrument used to measure the atmospheric pressure.</gco:CharacterString>
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      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
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                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
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          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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      <gmi:instrument>
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                <gco:CharacterString>salinometer</gco:CharacterString>
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            <gco:CharacterString>salinometer</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
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        </gmi:MI_Instrument>
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      <gmi:instrument>
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            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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      <gmi:instrument>
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          <gmi:identifier>
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              <gmd:code>
                <gco:CharacterString>temperature sensor</gco:CharacterString>
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            </gmd:MD_Identifier>
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          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
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      <gmi:platform>
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          <gmi:identifier>
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              <gmd:code>
                <gco:CharacterString>NOAA Ship Ronald H. Brown</gco:CharacterString>
              </gmd:code>
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          <gmi:description>
            <gco:CharacterString>Updated information from ICES for UNITED STATES platform

Ronald H. Brown
Flag : UNITED STATES - US (ISO Country Code)
Call Sign : WTEC
Title : NOAA Ship
Platform Class : Research vessel
IMO : 9105786
Pennant : R 104
Commissioned Date : 1997-07-19
Current Length : 83.5
Built : 1997
Information Source : http://www.moc.noaa.gov/rb/index.html (URL)
Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516

*General Comments:*
Name RESEARCHER II planned during build was never used.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
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    </gmi:MI_AcquisitionInformation>
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</gmi:MI_Metadata>